Using the arguments given in the text, uniqueness can not be shown for the Poisson equation
Answer:
If you can show that the homogeneous problem has a nontrivial (nonzero) solution , you are done. Then if there is any solution to the original problem, infinitely many more solutions can be obtained by adding arbitrary multiples of to .
To find a nontrivial solution, guess it. In particular, based on the boundary conditions for at and , guess that the nontrivial solution may be independent of . If you plug that assumption into the partial differential equation and boundary conditions, you can indeed find a nonzero solution.
If you solve the problem for a general mixed boundary condition, using separation of variables, you find that for many values of the coefficients and , but not all, there are nonunique solutions. However, there are none unless and have opposite sign.