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Fuel injection System
Safety
and Environmental
Issues Associated with JP-10
Chemical
name(s):
Tetrahydrodicyclopentadiene |
Tricyclo[5.2.1.0/2/6]decane |
exo-Trimethylenenorbornane |
Tricyclo5210-{2,6}-]decane |
Tetrahydro Dicyclopentadiene |
Endo-tetrahydrodicyclopentadiene |
ref.[ 1]
***It should be noted that
JP-10 has very little safety information associated with it.
OSHA gives virtually no data on exposure limits or other
health related information. Also, the MSDS for this material has not
been found thus far. One reason for this lack of description is that
JP-10 is used as a missile fuel and its properties may be unlisted or
classified.
The fuel
that will be used to make the fuel-air explosive in the fuel injection
system
will be JP-10, also known as tetrahydrodicyclopentadiene.
Because of this, precautions must be taken to
ensure that the fuel does not affect the handlers or the surrounding
environment. Per the sponsor for this
project, the safety and handling issues are based on the OSHA
(Occupational
Safety and Health Administration) guidelines.
Because
JP-10 is a fairly new fuel,
there has not been much data collected for it; therefore, the safety
guidelines
for JP-8 will be considered. JP-8
has
several potential symptoms that the handler(s) might face if they come
in
contact with the fuel. These
symptoms
are as follows:
-
Skin
irritation (itching, burning, rash,
redness)
-
Dermatitis
-
Headache,
fatigue, anorexia
-
Dizziness,
difficulty concentrating
-
Poor
coordination
-
Vomiting,
diarrhea, cramps
-
Drowsiness,
restlessness
-
Irritability
-
Loss
of consciousness
-
Death
-
Pneumonitis
The organs that are affected
by JP-8 are the skin, CNS (Central Nervous System), and
respiratory system.
OSHA also
provides guidelines for primary sampling for the JP-10.
The recommended media for the fuel is
charcoal tubing (100/50 mg sections, 20/40 mesh).
The analytical solvent for the JP-10 is
Carbon Disulfide and the alternative solvent is Carbon
Disulfide/Dimethylformamide. The
maximum
volume of the JP-10 should be 3 liters with a maximum flow rate of 0.2
liters/minute. The
current analytical
method for JP-10 is gas chromatography.
The
regulations and standards for explosives and blasting agents are also
given by
the OSHA website. Because
it will be
used as a fuel-air explosive, JP-10 can fall under this category. This
“” provides guidelines for storage,
handling, and transportation of the explosives and blasting agents.
The general
hazard warning for all explosives and blasting agents states,
“No person shall
store, handle, or transport explosives or blasting agents when such
storage,
handling, and transportation of explosives or blasting agents
constitutes an
undue hazard to life.”
The first
major subject involving safety of the explosives is their storage. The first provision of
this section states
that all classes of explosives should be stored in a magazine that
meets all
requirements. The
second provision
states, “Blasting caps, electric blasting caps, detonating
primers, and primed
cartridges shall not be stored in the same magazine with other
explosives.” The
next provision says
that the ground around the magazine shall be sloped for drainage and
the
surrounding land should be kept clear of brush, dried grass, leaves,
and other
materials for at least 25 feet.
The next pertinent subject is the
storage within the magazines where the jet fuel will be housed. One provision that is
important for the
project states, “Magazine floors shall be regularly swept,
kept clean, dry, and
free of grit, paper, empty used packages, and rubbish. Brooms and other
cleaning utensils shall not have any spark-producing metal parts.
Sweepings
from floors of magazines shall be properly disposed of. Magazine floors
stained
with nitroglycerin shall be cleaned according to instructions by the
manufacturer.” Another
important
provision set by OSHA is that all explosives be removed from the
magazines
where they are stored in the case of repairs to the magazines. An additional provision
that will be very
important to this project is in regards to misfires; it states,
“Explosives
recovered from blasting misfires shall be placed in a separate magazine
until
competent personnel has determined from the manufacturer the method of
disposal. Caps recovered from blasting misfires shall not be reused. Such explosives and caps
shall then be
disposed of in the manner recommended by the manufacturer.”
There are several general provisions
for transporting the jet fuel that are applicable to this project. One of them discloses that
no employee is
allowed to smoke, carry matches or any other flame producing device, or
carry
firearms or loaded cartridges while in or near an automobile
transporting
explosives; they also cannot drive, load, or unload such a vehicle in a
careless or reckless manner. Furthermore,
the fuel cannot be transferred from one vehicle to another one within
the
confines of any city, county, state, or other area without the fire and
police
departments’ prior notification.
The
vehicle transporting the fuel should have two fire extinguishers
located under
the driver’s seat, each with a rating of at least 10-BC. These extinguishers shall
be filled and ready
for use and checked periodically by a competent person.
The next pertinent set of provisions
given by OSHA is for the usage of the explosives and blasting agents. The first general
provision states that
smoking near the explosives shall not be permitted and that no one may
possess
matches or anything producing an open flame near the explosives; it
also says
that no one under the influence of alcohol, narcotics, or any other
dangerous
drugs may be allowed to handle the explosives.
The next important provision provided in
this section states, “Person
authorized to prepare explosive charges or conduct blasting operations
shall
use every reasonable precaution, including but not limited to warning
signals,
flags, barricades, or woven tire mats to insure the safety of the
general
public and workmen.” Another
provision
says that the blasting operations shall be conducted during daylight
hours. A further
precaution says, “Whenever blasting
is being conducted in the vicinity of gas, electric, water, fire alarm,
telephone, telegraph, and steam utilities, the blaster shall notify the
appropriate representatives of such utilities at least 24 hours in
advance of
blasting, specifying the location and intended time of such blasting. Verbal notice shall be
confirmed with written
notice.”
The “Warning
Required” provision set
by OSHA says that prior to the blast, the employer should require that
the
person in charge of the blast give a loud warning and make sure that
surplus
explosives are placed safely, all people and vehicles are at a safe
distance away
from the blast area, and that an adequate warning is given.
When dealing with blasting agents,
some additional provisions are required.
The building used for the blasting
agents should be made of concrete or
of other nonabsorbent materials and the building should be well
ventilated.
References:
[1] Chem Exper.com, ChemExper services
"JP-10"
URL:
http://www.chemexper.com/index.shtml?main=http://www.chemexper.com/search/cas/2825-82-3.html
[March 26, 2007]
Reference for JP-10
Information
Chemical Sampling Information: Jet Fuel
(JP10). (1996 October 7). Retrieved November 22, 2006 from http://www.osha.gov/dts/chemicalsampling/data/CH_248750.html.
Reference for JP-8
Information
Safety and Health Topics: Jet Fuel (JP8).
(2003 November 18). Retrieved November 22, 2006 from http://www.osha.gov/dts/chemicalsampling/data/CH_248748.html.
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